Carbonation of Concrete
Carbonation
of Concrete
Carbon
dioxide from air can react with the calcium hydroxide in concrete to form
calcium carbonate. This process is called carbonation, which is essentially the
reversal of the chemical process of calcination of lime taking place in a
cement kiln. Carbonation of concrete is a slow and continuous process
progressing from the outer surface inward, but slows down with increasing
diffusion depth.
Carbonatation
has two effects: it increases mechanical strength of concrete, but it also
decreases alkalinity, which is essential for corrosion prevention of the
reinforcement steel. Below a pH of 10, the steel's thin layer of surface
passivation dissolves and corrosion is promoted. For the latter reason,
carbonatation is an unwanted process in concrete chemistry. It can be tested by
applying phenolphthalein solution, a pH indicator, over a fresh fracture
surface, which indicates non-carbonated and thus alkaline areas with a violet
color.
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